It happened just before 9:30 p.m Saturday night.
An hour later, Ashland Police arrested Kevin Burns and Joshua Cordle for robbing Clark's Pump-n-Shop on 13th Street.
According to a press release, Burns is believed to have robbed the gas station at gunpoint, while Cordle drove the get away car.
Both men are in the Boyd County Detention Center and have been charged with robbery.
Cordle was also charged with wanton endangerment after police found his three-year-old son in the back of the car.
The child was not hurt.